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HomeMy WebLinkAbout7B - Discussion on fluoridation of drinking waterCITYOFBOULDER WATER RESOURCES ADVISORY BOARD NON-AGENDA ITEM MEETING DATE: Sept. 20, 2004 AGENDA TITLE: Staff presentation and WRAB discussion on fluoridation of drinking water. PRESENTER/S: Ned Williams EXECUTIVE SUMMARY: The issue of fluondahon of dnnkmg water is being reviewed by the Environmental Advisory Board (EAB) and they aze seekmg input from the WRAB on the issue Included m this packet item is a collechon of mforrnation mtended to provide background on the issue as rt has been evaluated by the WRAB and others in the past Fiscal Impacts: N/A Other Impacts: N/A Other Board and Commission feedback: The EAB has previously addressed this issue and is discussing whether to do so agam (Attachment A) The board is seekmg mput from the WRAB on the issue before proceedmg wrth any formal achon. The city of Boulder Attorney's office has evaluated cessation of fluondation achvities with respect to the ordmance that requires fluondation (Ordinance No. 3515). The results of that evaluahon are attached (Attachment B) The crty of Ft Collms has exammed the issue through the use of a Fluonde Techmcal Studies Group (FTSG). Information about the FTSG and their resultant study are mcluded (Attachments C and D). Public feedback: Public feedback has remazned controversial on the topia Summary Ytunutes from the May 21, 2001 WRAB meehng, when the WRAB previously discussed the issue, address the controversy surroundmg the topic (Attachment E) Staff recommendation: The staff is makmg no recommendation at ttus hme since the topic is presented for discussion only. Analysis: N/A Matrix of options: N/A Attachments: Attachment A Letter from the EAB requeshng WRAQB mput" Attachment B: Letter from city of Boulder Attorney's office addressing cessat~on of fluondation Attachment C Pnntouts of city of Ft Collms Web pages addressing fluondatron and the report produced by the FTSG Attachment D FTSG report Attachment E. WRAB Summary Mmutes from May 21, 2001 m which the WRAB considered the issue I-{ ~~cG~ ~ch-f ,4- ----Onginal Message----- From: Randali Weiner [mailto:ecolaw@bsuites.com] Sent: Monday, August 16, 2004 1:31 PM To: bart@westernresources.org; m~ller@westemresources.org Cc: Susan Iott; Kathie Joyner; John Putman; Alice Guthrie; Daniel Ziskin Subject: fluoride issue Dear Bart: In 1969, Boulder cihzens voted to add fluoride to the City's water supply by a 52% to 48% ma~onty In two prevtous elechons, Boulder voters had said "no" to addmg fluonde The ~ssue has conhnued to be conuoven~al dunng the thaty years that Boulder has been fluondaang its water More recently, Canada's foremost promoter of fluondahon, the Pres~dent of the Canadian Assoc~ahon of Dental Reseazch, stated that "for the past 15 years, I had refused to study the rox~cology mfonnauon that ~s readily available to anyone Pouomng our children was the furthest thmg from my mmd " ABC news suggested a few months ago that the science supportmg the e~cacy of addmg fluonde to dnnkmg water is "~unk" sc~ence In the past decade, over 60 commumhes m the U S and Canada have discontmued or re~ected water fluondahon, includmg Spokane, WA, Albany, N Y and Salt Lake C~ty The Envaonmental Advisory Board (EAB) previously addressed Ih~s issue We have d~scussed whether to do so agam However, I have been asked to fmd out what your Board's posihon ~s before we take any achon. Does your Board have the experGse or mclmat~on ro rev~ew the toxiwlogical impltcat~ons of contmumg to add fluonde to Bouldei s water supply~ Could you check tlus out for us~ Thank you, Bart Randy Wemer Cha~r, Env~ronmental Advisory Board Law Offices of Randall M Weiner, P C 1942 Broadway, Swte 408 Boulder, CO 80302 303-938-3773 303-442-6622-FAX ecolaw@bswtes com file://C:~Documents%20and%20Settings\willrl 000\Local%20Sethngs\Temp\GW}00001 HTM 9/10/2004 ~~~nrnevt~ ~3 CITY OF BOULDER, COLORADO Otlice of the City vMmev Atumc~pal Bwldmg I777 Brcudway Post Oflice Boe 79I BouldeG Cobrado SU305 Telephone(303~441-3020 Facs~nule(303)411-33i9 MEMORANDUM ~\~ , . ` ~ \ l,'\IY~J . ~ ~ y/~ //~ 1 / ~f 4 ~~ ~ ~~ TO: Mike Weil, Director of Env~ronmental Affairs FROM Sue Ellen Hamson, Assistant City Attorney ~~ ~-~y ~- `~ ~~ ~ - __ SUBJECT Cessation of Fluondation of Water Pursuant to Ordmance No 3513 DATE May 31, 2001 INTRODUCTION The City Attorney's office has revtewed Ordmance No 3513, mcludmg the Crty Charter requtrements for amendmg the ordmance. It is the opmion of this office that the ordmance is mandatory, and m order for the Crty to cease fluondahon, the ordmance must be repealed by a vote of the people NATURE OF THE ORDINANCE Ordmance No 3513 was passed by a vote of the people m November, 1969 The power to mihate legislatton is provided for m the State Constituhon, Art. V, Section l, and the City Charter, Section 37. The wordmg of the ordmance created a mandatory mrtiarive requmng the fluondahon of City water The operative sentence reads The Coordmator of pubhc facilihes . is hereby authonzed and dtrected to provide a means and to proceed with the mtroduchon of the fluonde ion mto the water supply fumished thts mumcipaltty m such quantihes as aze required to mamtam throughout the pipe distnbution system a fluoride ion concentration of approximately one part fluonde to one million parts water Ordmance No 3513, Secrion 1 There is no language which gives the City any discrehon in the matter The Coordmator is directed to proceed to mtroduce fluoride mto the water and to mamtam a speafic concentration. REPEAL OF THE ORDINANCE The City Charter provides in Sechon 54 that No ordmance that has been passed by a vote of the people under the imt~at~ve orhas recerved a favorable vote of the peopleunderthe referendum shall be repealed except by an ordmance submitted to a vote of the people This ord~nance was passed pursuant to the imttat~ve power, thus pursuant to Charter Section 43, a repeal of the ordmance requues Ctty Council to submit the ~ssue to a vote of the people by a c~tizen referendum In add~tion, cit~zens may, pursuant to Charter Sectton 37, mihate an ordmance to ehmmate or othenv~se change, fluondat~on. CONCLUSION If Public Works, the WRAB, the EAB, or cit~zens w~sh to d~scontmue fluondatmg City water, C~ty Counc~l must submit a referendum to the people to repeal Ordmance No 3513, or citizens may proceed on their own wuh an m~t~ative I~ P\V W 4 m-tlurord Ado Crty oY Nort C;ollms departments: uhlihes iluonde ~~ ~~~ C Page 1 oY 1 Drinking Water Fluoridation Overview ~ Technical__Study_Grou~ ~ Re~ort After almost two years of review, on July 15, 2003, City Council voted 4-3 to contmue the City's fluoridation program. The review process mcluded a comprehensive review of the scientific literature on fluoridation by the Fluoride Technical Study Group (FTSG), a group convened by the City and the Health District of Northern Lanmer County. This process included both technical review and public comment. The FTSG presented findinqs to the Larimer County Board of Health and the Water Board who then made recommendations to City Council. Council considered the recommendations of the Board of Health, the Water Board and the Board of the Health District, as well as comment from the public prior to the ]uly vote The Current Fluoridation Program As part of ongomg education about the current Fluondation program and the types of fluoride products used in fluoridation, the City provides the foilowing information. The City of Fort Coll~ns Utilities adds Fluoride to its water resulting in fluoride levels in the range of 0.7 to 1.2 milligrems of fluoride per liter of treated water, with a target amount of 1.0 mdligram per liter. This fluoridation has been part of the Utilities' treatment process for over 30 years, and is currently accomplished through the addition of hydrofluorosilicic acid. If you or members of your household are sensitive to fluonde or fluondation-related substances, or provide City water to an mfant younger than sfx months of age, please consult with your physician or other health expert regarding fluoridation-related precautions you may want to consider. For additional informat(on, please review the Fluoride Technical Study Group Report ----------------------------•----.. ........... .....---•----- -- ----------------------------- Site: pnv_ac~i_~ol~cy ~ discla~mer ~ Qc 1996-2004 ext nly ~ contact us ~ ~ Customer Service • Start/Stop/Change Your Serwce • Pavina Your Bill • Rate_s_&_Fees Generel Info • Contact_Us • Saving Energy • Water Conservation • Pro rems~erv_ices • On-line Publications Our Four Utilities • Electric • Stormwater • Wastewater • water ------------------------------------------•--............... ~ cv7M Ewt Sb1xns http //fcgov.com/util~ties/fluonde php~PHPSESSID=64b39b0e47164e66d31bcaba003clcfd 9/9/2004 City Servi4es_A-Z ~ Dep~ments ~ e-5erv~ces ~ Jobs ~ News ~ Public Re4ords home > departments > utdities > fluoride - - - - -- - - - ---- -~ - - -- -- - - - - . _ _ . -- - - - -- -- - - - - - l,ity o2 rort Lollins. departments utilines tluoncte report Yage 1 oY 1 te~t onlv ~ contact us ~ - ~~ Fluoride Technical Study Group Report Customer Service February 3, 2003 • Sta Stop/Change Your Service Overview ~ Technical Study Group ~ Report • pavinq Your B~II This report presents the consensus findings of the Fluoride Technical Study Grouo, • Rates & Fees which was charged with assessing the risks and benefits of community water Generai Info fluoridation. The report wdl help nsk managers (the L~nmer County_Board_of Health, the Water Board and the Fort Colhns City Councd) decide whether to cont~nue, alter • Contact Us or discontinue dnnking water fluoridation • Saving Enerqv The execu iv~ summary (PDF) Iists the five most important wnsiderations underlying ' Water Conservation the report and its findmgs, and then presents the findmgs themselves, which were •_Pro rams & Serwces developed in four categories~ • On-line Publications Our Four Utilities • The effectiveness of drinking water Fluondation in preventing cavities • Electric • The nsks of fluondation and of cumulatrve exposure from all sources • Stormwater . The costs and benefits of both addmg and not adding fluoride and . The potential for increased contaminant levels in drmkmg water due to the use of •~^!astewater hydrofluorosdiac aad in the fluondation process • Water Read the report's introduction (PDF), (revised Apnl 9, 2003) to learn more about the group's process, pnonties, literature review method, weight of evidence approach with uncertainties, important background information, and more. The full reoort (revised April 9, 2003), is available in a portable document format (PDF - 7.05 MB 227 pages) To read a PDF, you will need the free Adobe AsL2k~t Reader Review the Table of Contents for downloadabie sections of the report. To receive a copy of the report by mail, e-mad us (Please allow five busmess days, one copy per request.) For more information, call 221-6700 or e-mail -------- ----------- ------------- ----------------------- --------- --------- •-----..........------------------------._...... .....-----------........--- •-------- --- -----.._.....--°----...... ..... ..........._._..._.........._....._._. Site: privacy_pohcy ~ disclaimer ~ ~O 1996-2004 aM~r~cau.. http //fcgov.com/ut~lities/fluoride-report php 9/9/2004 Q Services A_Z ~ De~artments ~ e_Services ~ loks ~ N~ws ~ Pubhc Records home > departments > utdities > fluoride report - - -- - - - - - - - - -- - ~ ---- -- - -- - --- -- -- -- - ° -- - -- -- - - - City of Fort Collins departments utihhes techmcal study group Fluoride Technical Study Group Ov_erview ~ Technical Study Group ~ Report Customer Service • Start/Stop/Change Your Serv~ce The Techrncal Study Group fncluded nine community members with an interest m • paying Your Bdl community dnnking water fluoridation and with specific techrncal, medical or scientific capabilities The group met at least once a month between December 2001 • Rates_& Fees and December 2002 to: General Info . expiore information related to the costs and benefits of community dnnkfng-water Fluondatfon. This includes summarizmg what is known and not known about the risks and benefits of adding-or not adding-Fluoride to the dnnking water supply. • develop and present findmgs to the Lanmer County Board of Health and the F_o_rt Collins Water Board so they can offer mformed recommendations to the Fort Collins City Council. On luly 15, 2003, City Council voted 4-3 to contmue the City's Fluoridation progrem ~--------------------------- ------ ------ ---------------------------- ----------------- ---- ---- ---- -- -.._.. .. Site: pnyacy policy ~ disclaimer ~ ~_1996-2004 • Contact Us I • Saving Energy • Water Conser_v_ation • Pro rams_& Services • On-line Publications Our Four Utilities • Electnc • Stormwater • Wastewater • Water --------- --------------°----------- --------- ---------- ------------------ ---- ---..........__.------ n~r r~ena~a~x http //fcgov com/uhl~ties/fluoride-study php 9/9/2004 Page 1 of 1 ~ext only ~ cQntad us ~ _ - QtX Seryices A_Z ~ Departments ~ e=5ervices ~]obs ~ News ~ Publis_Records - -- - - - - -- - -- --- --- -- home > departments > utdities > technicai study group - - - - - -- - - - - -- -- -- -- - - - - - - --- - -- -- - -- - - - - - - - - - A~c~~,~,~~ ~ Table of Contents Table of Contents Executive Summary Introduction ... ...................... ui .......................1 Finding #1 - The Effectiveness of Drinking Water Fluoridation in Preventing Caries......... 9 H~stoncal Perspective . . . .... . . . . . . . . . . . .9 How Fluonde Works . . . . . . .. . .... . . . . . . .. . . .. 13 Ev~dence of Effectiveness of Commumty Water Fluondat~on . . . ... ... 14 Evidence of the Current Magmtude of Effechveness . . . 16 Studies of the EffecUveness of Commumry Water Fluondat~oa m Adults . . 18 Fluondahon-Ended S~[es m Wh~ch No Canes Increases Were Found. . .. 18 Gaps m Knowledge . . .. .. . . . . . . . 20 FINDINGS The EffecGveness of Dnnkmg Water Fluondahon m Preventmg Canes (Cavit~es) 21 Reference List . . .. . . . . . . . . . . . . . . . . . . 22 Finding #2 - The Risk of Drinking Water Fluoridation....., Total Exposure to Fluonde . . . FINDINGS Total Fluonde Exposure . . . . Review of Potent~al Adverse Health Effects Cancer . . .. . . FINDINGS Cancer. . . . . . Bone Fractures and Osteoporos~s . . . . . . FINDINGS Bone Effects. .. . Skeletal Fluorosis . . . . . . FINDINGS Skeletal Fluoros~s. . . . . Dental Enamel Fluorosis . . . . FINDINGS Dental Fluorosis. . . . . Thyroid Funct~on . . . . . . . FINDINGS Thyrmd Function . . . . . Immune System Effecu . . . . .. . . . . . FINDINGS Immunological Effects . . . . . . . Other Potential Health Effects . . . . FINDINGS Other Health EfFects . . . . . . . .. . Reference List . . . . . . .. . . . .. . . ........................................... 25 . 25 . . .. 30 . 30 . . 30 . 34 . . 34 - - - 37 . . . . 37 .. 40 . . . 40 . . . . . .44 ... . . .... 44 . . . .. .45 - - - - - - - . 45 . . . . . . 46 . . . . 46 .. 48 . . . ... .. 49 Finding #3 - Costs and Benefits, Includmg the Distribution of Costs and Benefits.......... 51 Cost-Effechveness of Commumry Water Fluondat~on ... . . . . . . . . . . . 51 Distnbut~onal Effects of Commumty Water Fluondation . . 55 Effectrveness and Cost-Effectrveness of Other Fluonde Modalmes Relauve to Commumty WaterFluondation . . . . . . . . 56 FINDINGS Costs and Benefits . . . . . . . 58 Reference List . . .. . . . . . . . . . . . . . . . 59 Finding #4 - The Potential for Increased Contaminant Levels Due to the Use of Hydrofluorosilicic Acid ............................................................................................................ 61 Background . . . . . . . . . . . . . . 61 Fluoride Sources . . . . . . 61 Fluonde Manufactunng Process . ' . . 61 Methods of Appl~cahon . . . . . . . 61 Table of Contents i Water Quality . . . . . . . . . . .. . 63 Analyhcal Informahon. . . . . . . . . . 63 Uncertvnhes . . .. . . ... .... .. . .66 FINDINGS The Potent~al for Increased Contacmnate Levels Due to the Use of Hydrofluoros~lw~c Acid . . . . . . . . . . . . . . .. . 71 Reference List . . . . .. . . . . . . . . . . . . . . . . ... . . . . 72 Appendix A-7 - Fort Collins Fluoride Technical Study Group Tiered Reference List........73 F~rst T~er . . . . . . ... . . 73 Other Lrterature Reviewed . . . . . . . . . . . . . . 74 Matenals Submitted by Members of the Publ~c. . . . . . . . . . . . . . 95 Appendix A-2 - Fluoride Mass Balance Calculations City of Fort Collins Water Treatment Facility ................ ......................................................101 Appendix 1- Effectiveness of Community Water Ftuoridation Methodological Approaches of "Tier One" and Other Reviews ... .....................................103 T~er 1 Reviews . . 103 Other Reviews . . . . . . . . 106 Appendix 2- Risks According to "Tier One "Reviews ........................................................109 Inuoduct~on . . . . . .109 Cancer . . . .. 110 Bone Fractures and Other Bone Effects . . . . . . . . . 119 Skeletal Fluorosis 127 Enamel (Dental) Fluoros~s 133 Other Health Effects 144 Appendix 3- Cost Effectiveness Studies ............................................................................. 159 Table 1 Cost-Effechveness Stud~es, U S . . . . . . . . . . 159 Table 2 Cost-Effechveness Studies, Other Countnes . . .. 163 Table 3 Other Delivery Strateg~es for Fluonde . . . .. .. 167 Table 4 Other Strategies for Pnmary Prevenuon of Dental Canes . . .. 170 Econom~c Analys~s of Commumty Water Fluondahon m Fort Collms, Colorado. . ... 172 References . . . . . 174 Appendix 4- The Pote~tial for Increased Contaminant Levels Due to the Use of Hydrofluorosilicic Acid ...........................................................................................................175 4 1 Matenal Safety Data Sheet Fluonde .. . . . . . . . . . . . . 175 4 2 Fluonde Manufactunng Process, Figures 1 and 2 . . . . . . . . . . . . . 181 4 3 Report Form 1 . . . . . . . . . 183 4 4 NSF Cerhficatwn . . . . . . . . . 184 4 5 Fort Collms Uttl~t~es Drmkmg Water Consumer Confidence Report, 2001 . 188 4 6 Fort Collms Ut~lit~es Dnnkmg Water Quahty Summary, 2001 and 2002 .. .... ..190 4 7 Results for Iron, Copper, Manganese, Zmc, Cadmmm and Nickel, Figures 3- 9 ... . 193 4 8 Arsemc Concentration m Fmished Water .. . . . ... 194 4 9 Peer Rev~ews of the Masters and Coplan Report . . .. . .. 198 4 10 Lead Data Regress~on Analysis . .. . . . . . . . . .. . .225 u Report of the Fort Colhns Techmcal Smdy Group - January 2003 Introduction In response to quesuons from the publ~c about the nsks, benefits and costs of community dnnkmg water fluondahon, the C~ty of Fort Colims convened the Fluoride Techmcal Study Group (FTSG) to fulfill ihe followmg responsibdity • To explore mformat~on related to the cosu and benefits of commumty dnnkmg-water fluondaUon, • To summanze what is known and not known about the nsks and benefits of addmg fluonde; • To summanze what is known and not known about the r~sks and benefits of not addmg fluonde, . To develop and present findmgs, • To base findmgs on the h~gh qual~ty scienh£c and techmcal mfoccnahon, • To work towazd consensus findtngs whenever possible, • To clanfy areas of a~eement and of d~sagreement about the ~mphcat~ons of [he mformahon, • To mtegrate pubLc mput mto the recommendations; and • To present data, consensus findmgs and areas of disagreement to the Boazd of Health and the Water Boazd so that these two boazds can offer mformed recommendaGons to the Fort Collms City Council The Fluonde Techrucal Study Group (FTSG) mcludes mne commumty members w~th an mterest m the quest~o~s surroundmg commumty dnnlung water fluondat~on and with spec~fic techntcal, med~cal or sc~entiFic capabtltt~es The FTSG members are Ed Carr, DC, MS Ch~ropractor and Wellness Counselor Bruce Cooper, MD, MSPH Medical D~rector Health Distnct of Northem Lanmer County Greg Evans, DDS Ped~atnc Denhst Gale McGaha M~ller, BS Water Qual~ty Serv~ces Manager Fort Colhns Ut~lrties Ram~ Naddy, PhD Env~ronmental Tox~colog~st ENSR Intemahonal Member of City of Fort Collms Water Boazd Kevm Gertig Cerhfied Colorado Water Works Operator A Water Producuon Manager Fort Collms Utdd~es Water Treatment Plant Adnenne LeBailly, MD, MPH * D~rector, Lanmer County Department of Health and Env~ronment John Re~f, DVM, MSc (Med) Professor Department of Env~ronmental Health Colorado State Umvers~ry Frank Vertucc~, PhD, MS Cemfied Semor Ecolog~st ENSR Intemahonal Vice President of the Lanmer County Board of Health ' Although Dr LeBailly's workload necess~tated that she wdhdraw from the rev~ew process m Summer 2002, she . was very achve m eazly meehngs and helped estabhsh gmdefines and rev~ew crrter~a She has conhnued to follow the group's praceedmgs Introduchon Process The Fluonde Techmcal Study Group (FTSG) met monthly as a full group, once each month, between December 2001 and November 2002 Dunng the report draftmg process m the latter 6alf of 2002, smaller subseu of FTSG members met frequently to draft vanous sect~ons of th~s document The FTSG met three times m December of 2002 to reach final consensus on the document In add~t~on, the FTSG held two public meetmgs m eazly 2002 to mvite mput and advice from the public before begmmng ~u work, and two in eazly 2003 to present and d~scuss report fmdmgs Throughout the process, the FTSG encouraged ongomg pubhc mput Of particulu note ~s the fact that at least one-third of the FTSG members exammed every techmcal s[udy, ~oumal azticle, newspaper aR~cle or v~deotape subm~tted by members of the publ~c All nme members reviewed those pubhc subtrussions deemed by any one member to be of s~gmficant sc~ent~fic or techmcal ment, and therefore worthy of mclusion m the FTSG del~berat~ons The techmcal and scienhfic mfocmahon was assembled, rev~ewed and distnbuted to the FI'SG by Susan Hewitt of the Health D~stnct of Northem Lanmer County, who also assisted m editmg and preparing the final draft report The FTSG also made efforts ro keep the public mformed of the work that was bemg accompl~shed All FTSG meehngs were open to the publ~c, although no pubLc comment was taken at these meehngs Summanes of the publ~c meetmgs and the FTSG meehngs were posted on a webstte mamtamed by the Fort Collms C~ty Ut~hty Deparknent AddR~onally, three sets of the reference matertals used by the FTSG were ava~lable for rev~ew by members of the publ~c at three locahons m Fort Colhns Pnorities In ds earlies[ meetmgs (and aRer publ~c meetmgs that eltcded important topics) the FTSG pnonhzed the key questions and centered its mquiry on developmg findmgs m response to these pnont~es The FTSG reviewed the scientific and techmcal I~terature for mformation about seven topics, s~x broad top~cs and one specific to a smgle d~sease end pomt • The effectrveness of dnnkmg water fluondahon • The nsk of dnnkmg water fluondaUOn • The nsk of cumulahve exposure [o fluoride (over time) from all sources, mcludmg dnnkmg water, • The costs and benefits of not fluondahng the dnnkmg water supply, mcludmg assessmg the d~stnbuhon wsts and benefits (equity) . The effechveness of altemative methods of deLvenng fluonde • The effechveness of addressmg fluondahon as a public health issue and the effecuveness of addressmg fluondauon as an mdividual choice . The nsk of ~mpacts to thyroid funct~on due to dnnkmg water fluondahon After generahng its m~hal draft of th~s report, the FTSG has consoUdated its findmgs mto these four top~cs 1 The effectrveness of drmkmg water fluondation 2 The nsks of dnnkmg water fluondahon and of cumulaUve exposure to fluonde from all sources, mcludmg dnnlung water, over ume (with spec~fic attenhon to cancer, bone fractures, skeletal fluorosis, dental fluorosis and thyroid function) 3 The costs and benefits of fluondahng the dnnk~ng water supply, and of not fluondaAng the dnnkmg water supply, mcludmg assessmg the d~stnbuhon costs and benefiu (eqmty), and mcludmg the costs and benefits of usmg altemahve methods to dehver fluonde 4 The potenUal for mcreased contammant levels m the dnnkmg water due to We use of hydrofluorosilicic acid m the fluondahon process , Report of the Fort Collms Fluonde Techmcal Study Group - Apn12003 Technical Studv Groua Literature Review Method From the start, ~t was acknowledged that the pubhshed sc~enhfic l~terature base on communrty water fluondation was enocmous and that rt was beyond the scope of this group to conduct a systematic review of thousands of pnmary studies The FTSG elected to use a hered approach to rev~ewmg the exisUng literature on water fluondahon, turning first to already conducted and pubLshed scientific literature research rev~ews and comp~lahons Only when a gap m the data became evident or when a spec~fic need for more mformahon was needed did the group tum to and evaluate pubLshed, peer-rev~ewed pnmary studies Imt~ally, a half dozen comprehens~ve Lterature reviews were located and shared by the FTSG, with addihonal studies and compilahons located dunng the process Ultimately, a tiered arrangement of the literature uhhzed by the FTSG was compiled • "Tier One" hterature were those by well-known, authontahve and unb~ased nahonal and mternat~onal pubLc health agenc~es such as the Umted States Pubhc Health Serv~ce, the World Health Orgamzat~on, the Umted States Centers for D~sease Control and Prevenuon, the Nat~onal Inshtutes of Health, the Medical Research Council of Great Bntam, and the BnGSh Nauonal Health Serv~ces Centre for Reviews and D~ssemmahon • The next her mcluded • Publ~shed luerature reviews and meta-analyses • Reports of pnmary studies pubhshed m peerrev~ewed ~oumals that were used to fill data gaps or when add~twnal explanahon was needed • Luerature rev~ews conducted by or contracted by mumc~pal, provmcial, or other local governmental enhues that were used for local decis~on makmg These were pnmanly used to idenhfy "T~er One" studies and primary l~terature • Other matenals cons~dered by the FTSG mcluded ed~tonals, commentary and fact sheets, some of whwh were suppl~ed by members of the public Concemmg "Tier One" and o[her hterature, each of these studies used d~fferent seazch and review strateg~es Some used expLcitly stated and highly systemahc methods to evaluate the scienhfic ment of studies, while others used more impl~cit and more sub~ectrve methods such as relymg on an evaluat~on of the quahty of the luerature by sub~ect matter experts The tiered reference list ~s provided m Appendix A- 1. Addrtional mformahon on the search and review strateg~es of many of the her one Lterature and other documents ~s presented m Append~x 1. Studv Criteria The FTSG, for the most part, hmited cons~deraaon to scienhfic stud~es of dnnkmg water fluondat~on at or uound 1 crulhgram per hter (mg/L) or 1 part per mill~on (ppm), because it is the target amount of fluonde added to the Fort Collms city water supply (range of 0 7- 1 2 mg/L w~th data mdicahng strmgent control at 1 0 mg/L) In some cases, studies where expenmental an~mals were dosed at a higher level or human ep~dem~olog~cal or pharmacolog~cal stud~es of populat~ons exposed to h~gher doses of fluonde were considered by the FTSG to better understand potent~al cumulatrve or dose-dependent effects Please note the terms part per million (ppm) and m~lligrams per l~ter (mg/L) aze used mterchangeably throughout th~s report. They aze more or less equrvalent and each temi is used by the Lterature c~ted by the FTSG In layman's terms 1 ppm or 1 mg/L fluonde represents one "drop" of fluonde m one m~llion "drops" of water Weiqht of Evidence Apuroach With Uncertainties Members of the FTSG used the weight of evidence approach m evaluahng scienhfic stud~es The EPA defines the we~ght of ev~dence approach as "Considerahons m assessmg the mterpretahon of published mformat~on about tox~city-qual~ty of teshng methods, size and power of study design, consistency of results across stud~es, and biological plausibility of exposure-response relat~onships and stat~sucal Introduct~on associahons" (http //www epa eov/OCEPAtemis~ Thus, all the sc~ent~fic Irterature on a topic ~s evaluated, with studies categonzed mro levels of better and lesser studies based on such vanables as degree of ineasurement accuracy, number of study sub~ecu, how data was collected, control of potenhal confoundmg factors and so on. The best studies get the most weight and the poorer studies less weight or disquahficat~on if a certam standard is not met Particulaz attent~on ~s grven when mulhple studies, by different reseazchers, usmg dtfferent methods, m vaned populahon groups reach similaz conclusions. Such findmgs generally corroborate hypotheses and aze particularly useful when lookmg for subtle health changes due to the large numbers of sub~ects measured The converse ~s also important, if mulhple stud~es show contrad~ctory pos~hve or negahve effects then no overall effect is d~scemable and hypotheses may be refuted before a lmk is made to potenhal hann or benefit The FTSG acknowledged uncertamhes aze mherent when sc~enhfic lrterature is evaluated Some members advocated for the precauhonary prmc~ple, defined by the EPA as"When mfortnahon about potent~al nsks is mcomplete, basmg dec~s~ons about the best ways to manage or reduce nsks on a preference for avoidmg unnecessary health r~sks mstead of on unnecessary ewnomic expendrtures" (http //www epa eov/OCEPAterms~ In other words, to ass~st the nsk managers, the weight of ev~dence ~s cons~dered as well as the magmtude of the calazruty that a worst-case scenano may produce if the evidence ~s flawed or maccurate The FTSG endeavored to create a balanced report for use by decision-makers that took mto account the most current and best available analysis of the weight of the scienafic ev~dence on the nsks and benefits of commumty water fluondahon The ~oup also acknowledged that there aze gaps m the knowledge and uncertvnties aze mherent m the ab~Lty to fully understand what may be subtle, yet unportant health effects that aze yet to be detected v~a a we~ght of the evidence approach Thus, the report mcludes stated u~certamties and azeas where add~honal research ~s needed to better understand the ttue benefits and nsks Strenaths and Limitations of Eoidemioloqv and Toxicoloqv Aaaroaches The potenhal rtsks of exposure to fluonde among human populahons can be evaluated m essenhally two ways In the first approach, laboratory ammals are tested under controlled conditions and exposed to known quanhhes of fluonde m water or food for varymg lengths of t~me Tox~wlogical studies attempt to denve dose-response relahonsh~ps between exposure to fluonde and some measure of orgamsmal response Measured responses may mclude moRahry, changes m growth, reproductrve capac~ty or the mc~dence of cancerous lesions. In some studies, rodents are exposed over their entae lifetime, up to two years These stud~es typically mclude hisrologic exammahon of tissues at the end of the study to detect m~croscop~c lesions m mult~ple organs Doses of fluonde gtven to ammals are often much higher than doses that would typ~cally be encountered by a person Exhapolahon of dose-response toxtcity tests m ammals to the pred~ct~on of human nsks from drmkmg water exposure to fluonde ~s complicated by many factors Fmdmgs must be extrapolated between the differences m doses used m an~mal studies and the range of human exposures assoc~ated w~th the consumphon of lmg/1(lppm) of fluonde m fluondated drmkmg water Ammal responses can vary compazed to human responses, and there is always uncertamty associated with extrapolat~on from test spec~es hke rodents to humans Absence of a dose-response relahonsh~p between a stressor and a response is cons~dered strong ev~dence that the stressor is not l~kely to cause a response However, the absence of any observed dose-response relat~onship between a stressor and a response does not prove that the stressor cannot cause a response The second approach to assessmg nsk to humans mcorporates epidemiolog~c studies of human populauons. These studies mvolve companng the mc~dence of vanous potent~al health effects among populahons exposed or not exposed to fluonde or comparmg the frequency of exposure to fluonde among persons wdh and wrthout a certam disease The advantages of the ep~demiologic approach aze that they Report of the Fort Collms Fluonde Techmcal Smdy Group - Apnl 2003 ue conducted m the species of mterest (humans), the exposures aze at relevant levels and the study ~s done by observahonal, rather than expenmental methods under "natural" condrt~ons The d~sadvantages of epidemiologic approaches aze that they may make u di~cult to accurately assess exposure over hme due to lack of mdrvidual level data about d~et, water consumpt~on pattems, fluonde concentrauons, etc These smdies are also sub~ect to a vanety of biases found m observational reseazch Pnncipal sources of b~as m epidem~ologic studies mclude I) confoundmg - where there may be exposure to another vanable that may be more common among those exposed that ~s aiso a nsk factor for the d~sease, resulting m an over- or under-eshmate of the true nsk, 2) selechon b~as due to an mab~hty to study enhre populahons, resultmg m a biased sample of part~c~pants whose exposures or disease pattems are not representahve of the populahon from which they are drawn, and 3) mformat~on bias, where mformahon about exposures, outcomes or other factors may be maccurate due to problems w~th recall, res~dent~al mob~lity, lack of adequate exposure data and other data madequac~es The FTSG reviewed the tox~wlogical and epidem~ological stud~es as mdependent hnes of evidence The we~ght of evidence findmgs are stronger when the tox~cological and epidemiological stud~es agree. However, erther lme of evidence may carry enough weight on its own to be convmcmg as to the benefits or nsks of a particulu substance In one example, the EPA's recent rulmg to lower the max~mum contammant level for azsemc m dnnkmg water from 50 µg/lrter to 10 µg/lrter came solely from epidemiologic stud~es md~catmg an mcreased nsk of cancer m exposed human populahons Also m the cancer azena, toxicologcal evidence may stand alone ~f a substance is tested repeatedly m several exper~mental test species (such as rats, mice, and hamsters) at suitable doses, and a spec~fic cancer is detected cons~stently m a sufficient proportion of test ammals The toxicolog~cal evidence is much stronger when the same substance ~s also shown, m a variety of genet~c test systems, to have DNA- damagmg effects (genotox~city) that have been associated w~th cancer m humans Risk and Benefit Assessment and Risk Manaaement The chazge of the FTSG was ro compile a report that assessed r~sks and benefits oF commumty water fluondaUOn m order to assist the nsk managers (~ e, the Lazimer County Boazd of Health, the C~ty of FoR Colhns Water Boazd, and the Fort Colhns C~ry Council) The FTSG found the followmg explanahon of risk management by the Medical Reseazch Counc~l of Great Brrtam to be paRiculazly useful "Once the nsks and benefits have been assessed, this mformahon must be set alongs~de other considerahons, such as the financ~al cost of the poltcy or achon, and a decision then made on whether to ~mplement the change Th~s ~s not simply a matter of science - it mvolves value ~udgments, and mdividuals may weight the nsks, benefits and attendant uncedamt~es differently If the decis~on must be taken at the commumty level (as with water fluor~dahon), ~t often falls to democrahcally elected representatrves and may follow wider publ~c consultaUOn and debate" Reference c~ted Medical Research Counc~l (2002) Workin~GrouQReoort Water Fluondat~on and Health London, U K John Wnght, p 7 Statutorv Authoritv for Fluoride Used in Communitv Water Fluoridation The Umted States Env~ronmental Protect~on Agency (EPA), under the Safe Dnnkmg Water Act (42 USC 300), promulgates the Nahonal Pnmary Dnnkmg Water Regulat~ons. These regulahons set the max~mum contammant levels (MCLs) for chemicals m fimshed water suppLed by pubhc water systems Based on a report by the Nahonal Reseazch Council, the EPA has establ~shed an MCL for fluonde of 4 0 mg/L The National Sanrtahon Foundahon (NSF) cernfies dnnkmg water additrves ~f khey aze shown to contnbute less than 10% of the MCL to the fimshed water supply for all dnnkmg water contammants regulated by the EPA As stated above, the level of fluoride m Fort Colims treated water supphes ~s stnngently conuolled at 1 0 ppm (range from 0 7 to 1 2 ppm) The FoR Colims Ut~liues Water Tceatment Program Introduct~on comphes with all regulatw~s set forth by the EPA for fluonde, uses products that aze certified by the NSF, and meeu or exceeds all recommendahons set forth by the Colorado Depaztment of Pubhc Health and Environment (CDPHE) as well as by the Umted States Centers for Disease Conhol and Prevenuon (CDC). Several mdrviduals at the miual publ~c meehngs suggested that fluonde should be treated as a drug that is added to commumry water and wondered why the Umted States Food and Drug Admm~strat~on (FDA) does not regulate fluonde m dnnkmg water The FTSG noted that FDA cons~ders the mtended use of producu when determmmg whether or not an "art~cle" ~s a drug, as opposed to a cosmet~c, a food or beverage, or none of these. The mtended use of the h~gh concentratwns of fluonde m toothpaste and other dental products meets the FDA's defimtion of a drug, i e, drugs aze "(A) articles mtended for use m the dia~os~s, cure, mmgahon, treatment, or prevenhon of disease and (B) art~cles (other than food) mtended to aFfect the structure or any funchon of the body of man or other an~mals" [FD&C Act, sec. 201(g)(1)J. Consistent w~th th~s definit~on, when fluonde is added to bottled water, the FDA regulates the product as a food, because of its mteaded use The EPA, rather than the FDA, has the authority m the U S to regulate mawmum levels of fluor~de m dnnkmg water In add~hon, the U S PubLc Health Service and state public health authonhes aze charged with ~ssumg recommendations regazdmg opt~mal levels of water fluor~dation for purposes of preventmg cazies, and the dec~s~on to fluondate water is left to the impacted populahon's elected o~c~als The FTSG did not address queshons of legal defimt~ons or the distnbuhon of regulatory authonty m mveshgat~ag the four outlmed ob~echves as previously stated Imaortant Backaround Information Relevant to the Fluoridation of Communitv Water in Fort Collins Coloredo History of Fort Collins Water Fluoridation Progrem In 1954, an ordmance to fluondate was presented to Fort Colhns voters, but d~d not receive suffic~ent votes to pass In 1966, Ihe Fort Collms C~ty Council adopted an ordmance proh~b~hng fluondahon unless approved by a vote of the publtc. Ctttzens voted m 1967 to authonze Ciry Council to add fluonde to Fort Colhns water supply system. That yeaz Fort Coilms began addmg dry sodium s~hcofluonde to the treated dnnkmg water supply at Water Treatment Plant #1 In 1992, the C~ty changed to a hqmd form of fluonde called hydrofluorosihc~c ac~d (HZS~F6). This practice contmues ro the present. Natural or Background Levels of Fluoride The FTSG felt ~[ was ~mportant for the dectsion-makers and the general publ~c to know that the source waters used by the C~ty of Fort Colhns (Cache La Poudre Rrver and Horsetooth Reservou) contam some natural amounts of fluonde The levels m untreated water range from 0 15 - 0 25 mg/L fluonde ion This is below the level considered by publ~c health authonUes to be `bphmal" for canes prevent~on Nahual fluonde is not removed dunng the water treatment process If the C~ty were to end ~u water fluoridation program, the dnnkmg water m Fod Collms would contmue to contam some fluonde Fort Gollins A~ea Water Providers In addit~on to Fort Collms UhLhes, there aze Uvee addihonal water uUlities servmg the Fort Collms azea (East Lanmer County Water Distnct, Fort Collms-Loveland Water D~stnct and North Weld County Water Dismct) Currently, Fort Colims Ut~hhes and these d~stncts fluondate at 1 mg/L Ne~ghbonng districts somehmes share watec If Fort Co1Lns Uhl~hes ceased to fluondate the water and some or all of the other d~stncts contmued to do so, some customers served by Fort Collms UtiLhes would recerve fluoride m the drmkmg water rangmg &om 0 2 to I 0 mg/L Customers would need to contact theu supplier to deteimme the level of fluonde m theu water Review of Water Treatment Process Chemistry Fort Colhns Utilit~es uses what ~s termed `Conventwnal TreatmenY for its two raw water sources Cache La Poudre River and Horsetooth Reservou waters aze blended and then treated usmg several different Report of the Fort Collms Fluonde Techmcal Study Group - Apn12003 chem~cals Each added treatment chem~cal ~s defined below and shown, begmntng from left to nght, on F~gure 1 The water treatment chem~cals used at the Fort Collms Water Treahnent Facihty aze purchased or prepazed m highly concentrated forms Many of these concentrated chemicals aze hazazdous pnor to the~r addit~on to the raw (untreated) water. However, once added to the raw water, these cheuucals aze diluted and become harmless, ~f not helpful. A fundamental concept m tox~cology that addresses th~s phenomenon was first descnbed in the sixteenth century by Pazacelsus, "All substances are po~sons, there ~s none wh~ch ~s not a potson The nght dose d~fferentiates a poison from a remedy " Thus, any review of the "safety° of dnaktng water add~hves must keep tn mmd that the dose determtnes whether the additrve is helpful or poisonous The reader should refer to F~gure I to rev~ew where each of the chem~cals descnbed below are added m the treatment process Raw Poudre Rrver Waler Raw Horsetooth Reservar Water C~brlns Obxitle (Cpr) PaWereO ActrvaOaC Ca~bon Lime (Ca(OHhI ~COn DIOMItlB (COe) Fbw Biend BnckgrouM FluonEe = 0 2 mgit ~ CkamBll ~Pb Stabon 1 ChbMe ~ms (CafOHhl Cerbon DbaOe (CO~ FhromalAek acM (HFS) (AGEaO FluaMe = 0 8 my/L) Fort Collins Water Treatment Facility Process Schematic and Location of Chemical Feed Points F~gure 1 Sample station To 2 ~-DistnbuGon (ss2) System Chlonne Diox~de (CIOZ) - used as a pre-oxidant for Horsetooth Reservo~r raw water to aid m the removal of certam contammants CIOZ ts made on s~te usmg a highly automated process Chlonne, sodmm chlonte, and water aze blended to fotm chlorme d~ox~de soluhon The solution vanes m strength and dosage based on raw water quahty CIOZ ~s a strong ox~dant and requ~res spec~al handlmg and feed eqwpment CIOZ d~sassociates to chlonte and chlorate ~ons as we-I as choru~e and hydrogen ions Powdered Act~vated Carbon (PAC) - PAC is used for removmg compounds that cause tas[e and odor PAG is added at dosages dependant upon raw water quai~ty cond~hons Carbon does not change chem~cal form after addit~on and ~s settled out oF the process after addmon Alum (AI~(SOJ> H~O) ~ Coagulatwn WBS~ Reservov Polymem (Ilocculantaidand fitlerad) Fbcculatwn 8 ~ Sedimenta6on Filtrahon East Reservov FluOriEe = 1 0 mdL ~ ~ FluonOe =1 0 mglL Introduchon Calcmm Hvdrox~de or Lime [Ca(OH)2] - L~me ~s added to the raw water to ad~ust the alkahmty of We raw water pnor to coagulahon AlkaLmty is a measure of the bu£fenng capac~ty of the water and is ryp~cally expressed as mg/I of calcmm carbonate (CaCO;) When hme is added to water, calcium ions are released and the alkahmty and pH go up (due to the mcrease m OH' that is released from the lime) Dosages vary from 5- 35 mg/L. Lune ~s very bas~c (pH => 10 5) Cazbon Dioxide (COZ) - COZ gas ~s used to ad~ust the pH of the raw water after Lme addihon (see L~me) COZ forms a weak acid when added to water - carbomc ac~d (HZC03) Alummum Sulfate or Alum (AIZ~SOa)s+ 14HZ0) - Alum ~s added to the water to coagulate the part~cles that are present m raw, untreated water Smce alum is posttrvely chuged, and most panc~les are negahvely charged, the particles agglomerate m the flocculat~on stage, and settle out m the umt process called sed~mentahon Alum is sltghtly ac~dic (pH of I% soluhon = 3.5) When alum ~s added to water, the salts dissociate to their respectrve trrvalent ions, Al"' and then form hydroxyl complexes {AI(HZO)6"} Polvmers (Cat~omc and Amomc)- Polymers aze added to the process to a~d m setdmg the lazger partwles that are formed m the coagulahon and flocculauon processes D~fferent rypes of polymers aze uUl~zed dependmg on the raw water source and quahty Dosages are applied at very low concentrations (0 O] - 0 2 mg/L) Smce polymers aze long chamed organ~c compounds, they do not change forcn and ue removed with the particles that aze settled and filtered out of the water Chlonne (Clz) - Chlonne is added to d~smfect the water after filuat~on Although chlonne ~s hazazdous as a gas form, when added to water, ClZ d~sassoc~ates to hypochlorous ac~d (HOCI') and hydrochlonc acid (HCl) The HOCI' ~s the forcn that dismfecu the water posages apphed are dependant upon many water quaLty factors, however regulat~ons requue that a mm~mum of 0 2 mg/L Cl2 remam m the water at the furthest end of the pipmg system that dehvers water [hroug6out our commumty Lime - Lime ~s also added at the clearwell to ad~ust the alkalm~ty of the firushed, potable water (38 - 40 mg/L as CaC03) Alkalmrty ~s a measure of the buffenng capac~ty and ~s typ~cally expressed as mg/L as calcmm cazbonate (CaC03) Agam, when hme ~s added to the water, calcmm ions are released and the pH goes up (due to the mcrease m OH" that is released from the l~me) Carbon D~ox~de - See above COZ is used to ad~ust the pH of the fimshed, potable water COZ fomis a weak ac~d when added to water - carbomc acid (HZC03) The final pH target for our commumry is stnctly controlled (pH 7 8- 8 0 umts) Fluorosil~cic Acid (HFS or HZSiFb) - Fluonde is added as a liqu~d w~th very precise metermg and flow measurement eqmpment L~qmd HFS ~s acid~c and once added to water, ~t dissoc~ates and will lower the pH of the solution In Fort Collms, both lime and cazbon d~ox~de aze added to mamtam stnct pH targets of Ihe fimshed water (see Figure 2) Report of the Fort Colims Fluonde Techmcal Smdy Group - Apnl 2003 Raw Poutlre RNer Water Fbw Floccula4on 8 Blend Coapuladon Setlimentetan FiNraLOn Raw Hwsetooth Resarvoir Background W~r Fluwitle = 0 2 mg/L Claanvell ~ ~ ~ S~atnn 1 HFS FEED WeS~ East (qdd~y Reservoir Raservo~r FluotlOe = 0 8 mglL) fluonde ~ 1 0 mglL Fluonde = 1 0 mglL Fort Collins Water Treatment Facility Process Schematic Sample Stadon To and 2 Distnbu Location of HFS (Fluoride) Feed ~SSZ> System F~gure 2 When HFS is added to water, hydrofluonc acid (HF) and s~l~con tetrafluonde (S~F4) aze formed Si6ca tetrafluonde is a gas that reacts quickly with water to form silic~c ac~d (HZS~O3) or sil~ca (SiOZ) and HF. The HF further dissociates to hydrogen and fluonde ion The concentrat~on of fluonde ~s stnctly controlled to a target level of 1 mg/L as fluonde ~on Overview of Fluoridation Chemistry M overnew of the chemistry of HFS addmon and what happens when ~t ~s dissolved m water is provided Another overview, wntten by an mdependent research group commissioned by the Bnus6 Fluondation Soc~ery can be found at htto //www l~v ac uk/bfshvrcreport ndf. For detailed recent sc~enhfic reviews of this issue, the reader should consult Urbansky and Shock, 2000 and Urbansky, 2002 Equilibrium The equil~bnum reaction between the strong ac~d hexafluorsil~cic acid (HFS) and water can be represented m chemical shodhand as. SiFb=' + 4HZ0 --~ Si(OH)4 + 4H~ + 6F The dissociahon of hexafuors~l~cate ion (S~F62') to the products on the nght hand s~de of the above equatton ~s considered to be complete at equilibnum at the normal pH of mumc~pal water supplies (pH > 7 0) In Fort Collms, the pH ~s sh~ctly mamtamed a[ a range of 7 8- 8 0 pH umts Complete d~ssociat~on at equil~bnum means chemists would repoR, based on the most conservahve (smallest) eqwhbnum constants m the chemical l~terature, that the ratto of StOH-0/SiF62" at pH 8 and a F- concentrahon of 1 mg/L would be about 1 x 10E26 07 That means that for every 1 molewle on non-dissociated S~FbZ" there are 10,000,000,000,000,000,000,000,000 molecules oF Si(OH)4 The resultmg concentrahon of S~FbZ" at equil~bnum m druilcmg water suppl~es where F' is adjusted w~th HFS to be 1 mg/L would be exceedmgly small («< ] P~ per tnll~on) Introducuon The t~me to achieve this equdibnum is not prec~sely known However, u ~s known to occur withm m seconds, ~f not mmutes, m complex aqueous chem~stry. Smce rt takes more than six hours for treated dnnkmg water to reach Fort Collms homes, there ~s more than ample hme for SiFbZ' to reach eqmLbnum (i e, to essenhally fully dissoc~ate) before any resident ingests t6e treated water Further val~dahon of the dissoc~at~on of HFS to F dunng Fort Collms water treatment comes from the chemical mass balance calculauons between the known amount of added HFS and the resulhng measured F- ~on concentraUon presented m Append~x A-2. If lazge amounu of HFS were not dissoc~ated u would be observed m the mass balance of HFS dosage versus the resultmg F~on concentrahon It ts important to put the mass balance findmgs mto the context that no more than 66% d~ssoc~ation was determmed by the Westendorf, 1975 thes~s c~ted by Masters et a12000 (See Fmdmg #4) Th~s thesis findmg is the "expenmental ev~dence" c~ted to call mto queshon the Irterature dissociahon constants suggestmg nearly 100% dissociat~on reported by Urbansky and Schock 2000, and Urbansky 2002 Smce the mass balance usmg the F" ion electrode method (ISE) is balanced withm 3% (Mass Balance CalculaUOns, Appendix A-2), the Fort Collms Water Treatment Fac~hry (FCWTF) momtonng data does not support the cla~m that 33% or more of the HFS added is undissoc~ated and remams m the water supply for Fort Colhns The mass balance reported an error of 3% and hence the analytical result demonstrates the d~ssociahon of the F~on Grven the prec~s~on m the values used for flow rate, applted dosage rate, HFS added m pounds per day, and the F" ~on concenhahon, the budget +/- 3%~s withtn measurement erzor The FCWTF data aze cons~stent w~th the predicnon of complete dissociahon of HSF based on chem~cal equihbnum [heory 10 Report of the Fort Collms Fluot~de Techmcal Study Group - Aprt12003 ~-~uG~ w~eh-~ ~ CITY OF BOULDER, COLORADO BOARDS AND COMMISSIONS MEETING SUMMARY FORM NAME OF BOARD/COMMISSION: Water Resources Adv~sory Board DATE OF MEETING: May 21, 2001 NAME/TELEPHONE OF PERSON PREPARING SiJMMARY: Robm Madel, 303-441-4073 NAMES OF MEMBERS, COUNCIL, STAFF AND INVITED GUESTS PRESENT: BOARD MEMBERS - Robert Fiehweg, Jeannette Hillery, Cal Youngberg, V~ck~ Naber, Gil Barth STAFF - Ned Williams, Chns Rudlan, Randy Cnttendon, Ridge Dorsey, Brad Segal and Robm Madel, secretary WHAT TYPE OF MEETING (BOLD ONE) (REGULAR] [SPECIAL] [QUASI-NDICIAL] Agenda Item 1- Call to Order The meehng was called to order at 7 07 p m Agenda Item 2- Approval of Apri116, 2001 Meehng Minutes Jeannette H~Ilerv moGoned to approve t6e minutes. V~cln Naber seconded. The motion passed unanimously, 4-0. Cal Youngberg was not there yet. Agenda Item 3- General C~hzen Partic~pahon There was none Agenda Item 4- Sta1'f update and discussion on drinkmg water fluor~dahon (Staff - Chris Rudkin and Randy Crittendon). Ned Wilhams mtroduced the topic and why ~t is bemg presented at the meehng He sa~d there have been a number of newspaper articles about fluondahon m dnvkmg water that has led to the Envuonmental Advisory Boazd (EAB) to discuss ~t at theu next meetuig on June 14, 2001 The EAB w~ll be takmg a vote of support or dissent about the ~ssue Chns Rudkm wanted to prov~de the WRAB with up-to-date mformahon about fluondahon of dnnking water He discussed several stud~es that had been perfom~ed to evaluate the effects of fluondahon He also d~scussed the recent decis~on by the Ft Collms Water Boazd to recommend discontmumg fluondahon of dnvkmg water He reviewed the lustory of fluondahon m Boulder and referenced the recent cit~zen survey that showed only 25% of respondents are sl~ghtly or strongly opposed to fluondahon WRAB Questions WRAB queshons covered the followu~g • The dec~s~on m Ft Collms • Appropnate mechamsms for fluondahon (~f inethods other than dnnkmg water are used) • Queshons/concerns about fluondahon from the Web stte • The survey results • The benefits of fluondahon • The pos~hons of the state and counry health departrnents • The s~tuahon m Colorado Spr~ngs • The existence of a mechaiusm to momtor for negahve ef~'ects • Negahve effects or potenhal negahve effects • The momtonng and distnbuhon system m place m Boulder • The source and form of the fluonde used m Boulder Citizen Particioat~on and WRAB Comment Water Resources Adv:sory Board Summary Mtnutes May 2!, 2001 Page ! Henrv Eaton, 2180 Sunshine Canyon Dr., Boulder, ts a retued denhst that led the campa~gn to get Boulder to fluondate its water m 1969 He sa~d m lus opuuon there has never been as effechve or safe a pubhc health ~ssue as t}us He said the ongmal studies came from Colorado Spnngs, which has three t~mes the dnnkmg water hmrt of nahually occurnng fluonde m theu water He said that fluorosis (whrte spots on teeth) was the only problem reported In lus dental prachce he used to see a lot of cavmes and tooth decay, especially m cluldren but he said it almost disappeazed after fluondahon began He ~s amazed by the comment made by the board m Ft Collms that Wey will save money by not admuustenng fluonde now that tooth decay is no longer a problem He feels ttus is a health matter and not an EAB matter and he sa~d he spoke with the c~ty attomey who agreed wrth hvn He explamed the process by wluch fluonde helps prevent tooth decay He spoke abou[ the previous elechons that attempted to end fluondahon and about how nasty those campa~gns go[ WRAB Comments Jeannette Hillery asked if any longevity studtes had been done m Colorado Spnngs Henry said he had been out of denhslry for 20 years but he didn't thmk any lmks had been found between d~seases and fluondahon He also pomted out that with 175 isulhon people recervmg fluondated water, ~f there were any lu~ks they would show up very cleazly The WRAB agreed that the issue belongs with the county and state health boazds The EAB meetmg w~ll be June 14, 2001 at 6 00 p m at 1720 13'" St Bob Fiehweg and Cal Youngberg agreed to attend the meehng If the EAB votes agau~st fluondahon, the City Council could decide to hold an elechon on rt, m which case they would probably have the WRAB evaluate it and make a formal recommendahon Agenda Item 5- Statt overview and discussion on t6e Industrial Pretreatment Program (Staf[- Ridge Dorsey). Rid e D~orsey gave a presentahon about the program He spoke from shdes that were mcluded m the packets He satd the same presentahon had been grven to a group of consultants and the Colorado Department of Public Health and the Envuonment Shdes covered the follow~ng topics The Defuuhon of Industnal Pretreatment The Goais of the Program Implementat~on of the Program PretreatrnentAuthonty PretreatrnentStandards Genera] Protvbit~ons of Pretreatrnent Spec~fic Protubihons of Pretreahnent Local Lucuts Federal Lumts The "nuts and bolu" of Local Luruts Enforcement Types of Noncomphance Factors Deteim~mng Response [o Noncompl~ance Tools to Deter Violators Pro-actrvrty m Boulder C~t~zen Participatiou and WRAB Comment There was none Water Resources Advtsory Board Summary Mtnutes May 21, 1001 Page 2 WRAB OaesLons WRAB queshons covered the followu~g • How compames can get mfo about the IP Progam • The PACE Program • The last co hance audit done b the c~ Agenda Item 6 - A. Matters Gom the Board • Jeannette Hillery said that she had gone to all of the South Boulder Creek reach meehngs and she's look~ng forwazd to the update that w~ll be grven next month She said the meehngs have been produchve and Alan Taylor is domg an outstandu~g ~ob B. Matters trom the Staff • Ned Williams reported that the Wonderland Creek pro~ect ~s underway and the ma~or excavahon work is done for the channel • Ned Wilhams reported that there would be three Barker Reservou meehngs dunng the summer The secretary will e-mail ffie dates of the meehngs to the WRAB members Agenda Item 7- Discussion of Future Meeting Dates and Agenda There are two meetutgs m June 1 The regulaz meehng on June 18, 2001, wluch w~ll cover the South Boulder Creek Floodplan, The 2002 budget, CIP and rate ~ncreases and the Inter-Governmental Agreement wrth Lafayette 2 A ~omt meehng wrth the TAB to discuss the Greenways Program CIP on June 25, 2001 at 7 or 7 30 p m at a locahon to be detemvned Agenda Item 8 - Ad~ournment The meetu~g was ad~ourned at 8 53 p m Date, Time, and Locat~on of Next Meeting: June 18, 2001, 7 00 p m, regular meetmg, at the City Yazds m the Cafetena June 25, 2001, Greenwa s Pro am CIP, at a tune and locahon to be detemuned Water Resources Advuory Board Summary Mrnutes May 21, 2001 Page 3